>>280833706No. Misato promised Shinji that she'd fuck him.
>>280833440He wasn't angry at the concept of sex, he was angry that Misato used sex as form of escapism, which can also be interpreted as Misato betraying him, since that meant she didn't think of him as special.
It's also possible that he was angry at Misato because she reminded him of himself. Shinji using his sexual fixation on Asuka's body to find comfort and escape from reality is a major theme in their relationship.