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Misaki - started out as a part-time worker at the resort, then Owner-san's personal assistant, and now is the main event organizer
Luna - Weirdo who may or may not be from the moon, a researcher and the closest thing VV has to a resident mad scientist
Tamaki - fashion designer and alcoholic who designs all of the swimsuits, Helena's friend
Fiona - 'European' princess who came to the island to marry Owner-san
Nagisa - Actress and Misaki's older sister, came to the island to be Misaki's chaperone, huge tsundere
Kanna - Oni who came to the island to hang out with humans, old 'friend' and rival of Nyotengu
Monica - dealer-in-training who runs the casino
Sayuri - nurse who runs the island clinic, got fired from her old job because all patients kept getting boners when she tended to them
Patty - native of one of the neighboring islands who swam across to Venus Island, runs the island radio station
Tsukushi - smelly NEET and artist who came to draw pictures and manga of the other girls
Lobelia - aristocrat from Fiona's country, has a one-sided rivalry with Fiona and wants to 'win' Owner-san before the princess
Nanami - Misaki's friend and photographer
Elise - Efficiency specialist who came to help Owner-san better manage his many duties, now his personal assistant and squeeze toy (she sleeps in his bed every night because it helps keep him calm)
Koharu - runs the island hot springs
Amy - tech nerd, IT support for the island
Shandy - bartender, runs the pool bar, 'Shandy' is not her real name, Chinese
Yukino - Gyaru who idolized Tamaki
Shizuku - Fox spirit who pretends to just be a cosplayer to avoid suspicion about her tail and ears
Reika - professional swimmer who came to the island to train, hired as the official life guard for the island, swim times keep dropping due to her boobs growing so big
Meg - fuck, I dunno
Azusa - Some connection to Tsukushi, seems like a biker chick.

Updated