I can count on one hand the amount of times I've been ambushed in solos. If you're getting shot in the back of the head, it's a skill issue.
Literally just play like you're always being chased. When you walk into a building, sit around the corner from the door and watch to see if anybody is following. If you have to kill a drone, look around before you loot. Set up a perimeter. Walk when you first approach a poi or building. Try not to cross open areas, and if you have to, sprint the entire way and use stims to keep up the pace. Bring smokes and lure grenades for a free extract.