>>2928030Me again. Glad to be of help. I take it your setup is a metal flue/chimney pipe in an existing brick or ceramic pipe.
Is the metal chimney isolated? There are typically 3 types of steel chimneys: un-insulated, 25 mm insulation or 50 mm insulation. The insulated ones will have a center stainless steel pipe surrounded by 25/50 mm insulation and an outer metal pipe (typically painted black).
If yours is an isolated one, you can use an epdm rubber surround around the steel chimney to get a 100% seal i combination with vermiculite, silicate sheet or metal.
What country are you in if you don't mind me asking? Helps to know what's available in your region.